This text is based on Metal Alkoxides (Academic Press, 1978), and has been updated and expanded to include developments in this growing field from the past 20 years. Coverage includes homometallic alkoxides; heterometallic alkoxides; x-ray crystal structures of alkoxo metal compounds; metal oxo-alkoxides; metal aryloxides; and their industrial applications in such areas as microelectronics, ceramics, non-linear optical materials, high-temperature superconductors, and specialized glasses. Intended as a reference for those working in the field, as well as for use as a supplementary text for advanced inorganic chemistry courses.